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The phosphate sulfates are mixed anion compounds containing both phosphate and sulfate ions. Related compounds include the arsenate sulfates, phosphate selenates, and arsenate selenates.
Some hydrogen phosphate sulfates are superprotonic conductors.
List
chem | mw | crystal system | space group | unit cell | volume | density | comment | references | |
---|---|---|---|---|---|---|---|---|---|
Sanjuanite | Al2(PO4)(SO4)(OH)·9H2O | [1] | |||||||
Hotsonite | Al11(SO4)3(PO4)2(OH)21 · 16H2O | triclinic | a=11.23, b=11.66 c=10.55 α=112° 32′, β=107° 32′ γ=64° 27′ | refract: α = 1.519 γ = 1.521 | [2] | ||||
Arangasite | Al2F(PO4)(SO4)·9H2O | monoclinic | P2/a | a = 7.073, b = 9.634, c = 10.827, β = 100.40°, Z = 2 | 725.7 | [3] | |||
peisleyite | Na3Al16(SO4)2(PO4)10(OH)17 · 20H2O | monoclinic | a 13.31, b 12.62, c 23.15, β 110.0°, Z = 2 | discredited | [4] | ||||
peisleyite | Na2Al9[(P,S)O4]8(OH)6·28H2O | triclinic | P1 | a = 9.28, b = 11.98, c = 13.25, α = 91.3, β = 75.6, γ = 67.67°, Z = 4 | 1308 | [5] | |||
Woodhouseite | CaAl3(PO4)(SO4)(OH)6 | trigonal | R3m | a = 6.993, c = 16.386 | 693.95 | 3.0 | Uniaxial (+) nω = 1.636 nε = 1.647 Birefringence: δ = 0.011 | [6] | |
Ardéalite | Ca2H(PO4)(SO4)•4H2O | monoclinic | a = 5.721, b = 30.95, c = 6.265, β= 117.26° Z = 4 | 986.11 | 2.32 | [7] | |||
Destinezite Diadochite | Fe2(PO4)(SO4)(OH)•6H2O | triclinic | P1 | a = 9.570, b = 9.716, c = 7.313, α = 98.74°, β = 107.90°, γ = 63.86° Z = 2 | [8] | ||||
bohuslavite | FeIII4(PO4)3(SO4)(OH)(H2O)10·nH2O (5 ≤ n ≤ 14) | triclinic | P1 | a = 13.376 b = 13.338 c = 10.863 α = 92.80, β = 91.03, γ = 119.92°, Z = 2 | 1675.7 | pink | [9] | ||
Borickyite | (Ca,Mg)(Fe3+,Al)4(PO4,SO4,CO3)(OH)8·3–7.5H2O | [10] | |||||||
Camaronesite | [Fe3+(H2O)2(PO3OH)]2(SO4)·1–2H2O | trigonal | R32 | a = 9.0833, c = 42.944, Z = 9 | 3068.5 | [11] | |||
Fe3+4(PO4)3(SO4)(OH)·18H2O | triclinic | P1 | a=13.376, b 13.338, c 10.863, α 92.80, β 91.03, γ 119.92° | 1675.7 | [12] | ||||
vanderheydenite | Zn6(PO4)2(SO4)(OH)4·7H2O | monoclinic | P21/n | a = 6.204 b = 19.619, c = 7.782, β = 90.67° | 947.1 | biaxial (–) α = 1.565, β = 1.580 γ = 1.582. 2V = 39.8° | [13] | ||
Svanbergite | SrAl3(PO4)(SO4)(OH)6 | trigonal | R3m | a = 6.97, c = 16.59 Z=3 | 697.98 | 3.2 | Uniaxial (+) nω = 1.631 - 1.635 nε = 1.646 - 1.649 Birefringence: δ = 0.015 | [14] | |
Birchite | Cd2Cu2(PO4)2(SO4) ·5H2O | a = 10.489 b = 20.901 c = 6.155 Z=4 | 1349.6 | 3.647 | biaxial positive,
nα = 1.624, nβ = 1.636, nγ = 1.669, 2Vcalc = +63°. |
[15] | |||
Corkite | PbFe3(OH)6SO4PO4 | trigonal | R3m | a = 7.32, c = 17.02 Z=3 | 781.2 | 4.295 | Uniaxial (-) nω = 1.930 nε = 1.930 n = 1.93 - 1.96 Birefringence 0.03 | [16] | |
BaAl3(PO4)(SO4)(OH)6 | trigonal | R3m | a = , c = Z=3 | [17] | |||||
hinsdalite | (Pb,Sr)Al3(PO4)(SO4)(OH)6 | [18] | |||||||
Tsumebite | Pb2Cu(PO4,SO4)(OH) | [19] | |||||||
Delvauxite | CaFe43+(PO4,SO4)2(OH)8·4–6H2O | [20] | |||||||
Rossiantonite | Al3(PO4)(SO4)2(OH)2(H2O)10·4H2O | triclinic | P1 | a = 10.3410, b = 10.9600, c = 11.1446, α = 86.985, β = 65.727, γ = 75.064°, Z = 2 | 1110.5 | [21] | |||
Schlossmacherite | (H3O,Ca)Al3(AsO4,PO4,SO4)2(OH)6 | [22] | |||||||
Arthurite | Cu(Fe3+)2(AsO4,PO4,SO4)2(O,OH)2·4(H2O) | [23] | |||||||
cobaltarthurite | [23] | ||||||||
Phosphoinnelite | Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3 | triclinic | P1? | a = 5.38, b = 7.10, c = 14.76; α = 99.00°, β = 94.94°, γ = 90.14° Z = 1 | 555 | 3.82 | biaxial (+), α = 1.730, β = 1.745, and γ = 1.764, 2V 90° | [24] | |
Francolite | (Ca, Mg, Sr, Na)10(PO4, SO4, CO3)6F2–3 | [25] | |||||||
Al4(UO2)2(PO4)4(SO4)(OH)2 · 18H2O | [26] | ||||||||
Al4(UO2)2(PO4)4(SO4)(OH)2 · 20H2O | [26] | ||||||||
Coconinoite | Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 20H2O | monoclinic | C2/c | a =12.45, b = 12.96, c = 17.22, β = 105.7° | [26] | ||||
xiangjiangite | Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 22H2O | tetragonal | a = 7.17 Å, b = 7.17 Å, c = 22.22 Å Z=1 | 1,142 | Biaxial (-) nα = 1.558 nβ = 1.576 nγ = 1.593 2V: 87° | [27] |
Artificial
chem | mw | crystal system | space group | unit cell Å | volume | density | comment | references |
---|---|---|---|---|---|---|---|---|
[H4N+]2·HSO4−·H2PO4− | [28][29] | |||||||
NH4(HSO4)0.45(H2PO4)0.55 | orthorhombic | [30] | ||||||
18-crown[6]·[NH4][H2PO4]0.5[HSO4]0.5·H2O | orthrhombic | F2dd | a=8.710 b= 28.868 c=31.206 Z=16 | 7846 | 1.346 | dehydrate at 70° | [31] | |
[(C2H5)4N+]2·HSO4−·H2PO4− | Monoclinic | C2/c | a = 28.0787 b = 11.8671 c = 14.1533 β = 100.739° Z=8 | 4633.46 | 1.303 | colourless; decompose at 353K | [32] | |
(NH2CH2COOH)3(H2SO4)0.7(H3PO4)0.3 | monoclinic | called TGSP; colourless; ferroelectric, curie point 51 °C; pyroelectric | ||||||
Na(HSO4)(H3PO4) | monoclinic | P 21 | a = 5.449, b = 6.832, c = 8.718, β = 95.88°, Z = 2 | 322.8 | [33] | |||
K2(HSO4)(H2PO4) | monoclinic | P 21/c | a = 11.150, b = 7.371, c = 9.436, β = 92.29°, Z = 4 | 774.9 | [33] | |||
K4(HSO4)3(H2PO4) | triclinic | P 1 | a = 7.217, b = 7.521, c = 7.574, α = 71.52°, β = 88.28°, γ = 86.20°, Z = 1 | 389.1 | [33] | |||
K4(PO2F2)2(S2O7) | 534.46 | monoclinic | C2/c | a = 13.00, b = 7.543, c = 19.01, β = 130.07°, Z = 4 | 1426.5 | 2.489 | colourless; pyrosulfate + difluorophosphate | [34] |
K3[O3SOPO2OSO3] | [35] | |||||||
H1−xTi2(PO4)3−x(SO4)x (x=0.5–1) | [36] | |||||||
Na2MgTi(SO4)(PO4)2 | trigonal | R3c | a=8.4796 c=21.8091 Z=6 | 1358.1 | 2.818 | [37] | ||
K2MgTi(SO4)(PO4)2 | cubic | P213 | a=9.8743 Z=4 | 962.84 | 2.872 | [37] | ||
Ca10-xNax(PO4)6-x(SO4)xF2 | monoclinic | [38] | ||||||
NaFe2(PO4)(SO4)2 | hexagonal | R3c | a=8.4243 c=21.973 | [39] | ||||
NaFe1.4V0.6(PO4)(SO4)2 | [40] | |||||||
[Ni(C14H10N4)3]4(PO4)2(SO4) (C14H10N4=2,2'-bi-1H-benzimidazole) | 3331.96 | cubic | I43d | a = 24.964 Z=4 | 15558 | 1.423 | green | [41] |
Rb2(HSO4)(H2PO4) | monoclinic | P21/n | a=7.448, b=7.552, c=7.632, β=100.47°, Z=2 | 422.1 | [42][43] | |||
Rb2(HSO4)(H2PO4) | monoclinic | P21/c | a=11.555, b=7.536, c=9.593, β=91.56, Z=4 | 853.0 | at 160K | [43] | ||
Rb4(HSO4)3(H2PO4) | orthorhombic | P21212 | a=7.612, b=14.795, c=7.446, Z=2 | 838.6 | [42][43] | |||
18-crown[6]·Rb[H2PO4]0.5[HSO4]0.5·3H2O | monoclinic | C2/c | a=19.802 b=8.447 c=25.777 β=101.00° Z=8 | 4232 | 1.572 | dehydrate at 70° | [31] | |
Rb2MgTi(SO4)(PO4)2 | [37] | |||||||
Sr4(PO4)2SO4 | [44] | |||||||
NaZrMg(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
NaZrCo(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
NaZrNi(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
NaZrCu(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
NaZrZn(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
NaZrAl(PO4)2(SO4) | hexagonal | R3c | [45] | |||||
NaZrFe(PO4)2(SO4) | hexagonal | R3c | [45] | |||||
H3OSb2(SO4)2(PO4) | triclinic | P1 | a=5.134 b=7.908 c=12.855, α=81.401° β=87.253° γ=86.49° | [46] | ||||
KSb2(SO4)2(PO4) | triclinic | P1 | a=5.1453 =7.9149 c=12.6146, α=82.054° β=87.715° γ=86.655° | [46] | ||||
RbSb2(SO4)2(PO4) | triclinic | P1 | a=5.1531 b=7.957 c=12.845, α=81.801° β=87.676° γ=86.703° | [46] | ||||
Cs2(HSO4)(H2PO4) | cubic | ao=4.926 | >105 °C but can be supercooled | [47] | ||||
Cs2(HSO4)(H2PO4) | monoclinic | P21/n | a = 7.856 b = 7.732 c = 7.827, β= 99.92° Z=2 | 468.3 | 3.261 | can substitute 2.3% ammonium; proton conductivity at 110 °C is 3×10−3 Ω−1cm−1 | [48][49] | |
Cs3(HSO4)2(H2PO4) | monoclinic | C2/c | a=19.824 b=7.859 c=19.047 β=100.20° Z=4 | 1387.2 | 3.302 | stable against water solution 298-313K; phase transition at 411K | [50] | |
Cs4(HSO4)3(H2PO4) | monoclinic | C2/c | a=19.945 b=7.8565 c=8.9949 β=100.119° Z=3 | 1387.5 | 3.301 | colourless | [51][52] | |
Cs5(HSO4)2(H2PO4)3 | cubic | I43d | a=14.5668 | over 381K goes to tetragonal a=4.965 c=5.016 | [53] | |||
Cs6H(HSO4)3(H2PO4)4 | cubic | I43d | a=14.4758 | 3033.38 | 3.236 | colourless | [54] | |
Cs5(HSO4)3(H2PO4)2 | monoclinic | C2/c | a=34.07 Å,b=7.661,c=9.158,β=90.44° | 2390 | 3.198 | [55] | ||
18-crown[6]·Cs[H2PO4]0.5[HSO4]0.5·3H2O | monoclinic | C2/c | a=19.840 b=8.460 c=26.19 β=101.14 Z=8 | 4313 | 1.689 | dehydrate at 70° | [31] | |
CsNH4(HSO4)(H2PO4) | [56] | |||||||
Cs3NH4(HSO4)3(H2PO4) | [56] | |||||||
Cs2MgTi(SO4)(PO4)2 | [37] | |||||||
Ba4(PO4)2SO4 | [44] | |||||||
NaBa6Zr(PO4)5SO4 | cubic | I43d | a = 10.5449 Z=4 | 1172.54 | eulytite mineral structure | [44] | ||
Ba2Sr2(PO4)2SO4 | [44] | |||||||
Ba3Sr(PO4)2SO4 | [44] | |||||||
Ce2O(HPO4)2(SO4). 4H2O | CeIV | [57] | ||||||
Ce2O(HPO4)2.4(SO4)0.6. 2H2O | CeIII | [58] | ||||||
[enH2]0.5[CeIII(PO4)(HSO4)(OH2)] | monoclinic | P21/a | a=12.999 b=7.150 c=9.212 β=95.33 | cream colour | [59] | |||
KSr2Eu(PO4)2SO4 | [44] | |||||||
RbSr2Eu(PO4)2SO4 | [44] | |||||||
CsSr2Eu(PO4)2SO4 | [44] | |||||||
[enH2]0.5[Ho(HPO4)(SO4)(H2O)] | monoclinic | P21/a | a = 12.938 b = 6.834 c = 9.100 β = 88.12° | [60] | ||||
Pb2Mg2(PO4)2SO4 | [44] | |||||||
MgPb3(PO4)2(SO4) | cubic | I43d | a = 10.299 Z=4 | 1092.4 | 5.67 | [61] | ||
CaPb3(PO4)2(SO4) | cubic | I43d | a = 10.296 Z=4 | 1091.5 | 5.77 | [61] | ||
MnPb3(PO4)2(SO4) | cubic | I43d | a = 10.258 Z=4 | 1079.4 | 5.92 | [61] | ||
CoPb3(PO4)2(SO4) | cubic | I43d | a = 10.356 Z=4 | 1110.6 | 5.78 | [61] | ||
NiPb3(PO4)2(SO4) | cubic | I43d | a = 10.434 Z=4 | 1135.9 | 5.65 | [61] | ||
CuPb3(PO4)2(SO4) | cubic | I43d | a = 10.422 Z=4 | 1132.0 | 5.70 | [61] | ||
ZnPb3(PO4)2(SO4) | cubic | I43d | a = 10.449 Z=4 | 1140.8 | 5.67 | [61] | ||
CdPb3(PO4)2(SO4) | cubic | I43d | a = 10.315 Z=4 | 1097.5 | 6.17 | [61] | ||
SrPb3(PO4)2(SO4) | cubic | I43d | a = 10.369 Z=4 | 1114.8 | 5.93 | [61] | ||
Th2(PO4)2SO4·2 H2O | decompose 450 °C | [62] |
Organic derivatives
A catenated sulfophosphate has the sulfur and phosphorus joined by an oxygen atom. In biochemistry, metabolism of sulfate may use such a group, for example with adenosine-5'-phosphosulfate.[63]
References
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- ^ Beukes, Gerhard J.; Schoch, Aylva E.; Van der Westhuizen, Willem A.; Bok, Louis D. C.; Bruiyn, Hendrik (1984-10-01). "Hotsonite, a new hydrated aluminum-phosphate-sulphate from Pofadder, South Africa". American Mineralogist. 69 (9–10): 979–983. ISSN 0003-004X.
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- ^ Peacor, Donald R. (1999). "Destinezite ("Diadochite"), Fe2(PO4)(SO4)(OH)·6H2O: Its Crystal Structure and Role as a Soil Mineral at Alum Cave Bluff, Tennessee†". Clays and Clay Minerals. 47 (1): 1–11. Bibcode:1999CCM....47....1P. doi:10.1346/CCMN.1999.0470101. ISSN 0009-8604. S2CID 98406559.
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- ^ Frost, Ray L.; Palmer, Sara J.; Xi, Yunfei (June 2012). "Is the mineral borickyite (Ca,Mg)(Fe3+,Al)4(PO4,SO4,CO3)(OH)8·3–7.5H2O the same as delvauxite CaFe43+(PO4,SO4)2(OH)8·4–6H2O?". Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 92: 377–381. Bibcode:2012AcSpA..92..377F. doi:10.1016/j.saa.2012.02.102. PMID 22446787.
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