A sustainable approach for the reliable and simultaneous determination of terpenoids and cannabinoids in hemp inflorescences by vacuum-assisted headspace solid-phase microextraction

Environmental chemistry is the scientific study of the chemical and biochemical phenomena that occur in natural places. It should not be confused with green chemistry, which seeks to reduce potential pollution at its source. It can be defined as the study of the sources, reactions, transport, effects, and fates of chemical species in the air, soil, and water environments; and the effect of human activity and biological activity on these. Environmental chemistry is an interdisciplinary science that includes atmospheric, aquatic and soil chemistry, as well as heavily relying on analytical chemistry and being related to environmental and other areas of science.

Environmental chemistry involves first understanding how the uncontaminated environment works, which chemicals in what concentrations are present naturally, and with what effects. Without this it would be impossible to accurately study the effects humans have on the environment through the release of chemicals.

Environmental chemists draw on a range of concepts from chemistry and various environmental sciences to assist in their study of what is happening to a chemical species in the environment. Important general concepts from chemistry include understanding chemical reactions and equations, solutions, units, sampling, and analytical techniques.^[1]

Contaminant

A contaminant is a substance present in nature at a level higher than fixed levels or that would not otherwise be there.^[2]^[3] This may be due to human activity and bioactivity. The term contaminant is often used interchangeably with pollutant, which is a substance that detrimentally impacts the surrounding environment.^[4]^[5] While a contaminant is sometimes a substance in the environment as a result of human activity, but without harmful effects, it sometimes the case that toxic or harmful effects from contamination only become apparent at a later date.^[6]

The "medium" such as soil or organism such as fish affected by the pollutant or contaminant is called a receptor, whilst a sink is a chemical medium or species that retains and interacts with the pollutant such as carbon sink and its effects by microbes.

Environmental indicators

Chemical measures of water quality include dissolved oxygen (DO), chemical oxygen demand (COD), biochemical oxygen demand (BOD), total dissolved solids (TDS), pH, nutrients (nitrates and phosphorus), heavy metals, soil chemicals (including copper, zinc, cadmium, lead and mercury), and pesticides.

Applications

Environmental chemistry is used by the Environment Agency in England, Natural Resources Wales, the United States Environmental Protection Agency, the Association of Public Analysts, and other environmental agencies and research bodies around the world to detect and identify the nature and source of pollutants. These can include:

Heavy metal contamination of land by industry. These can then be transported into water bodies and be taken up by living organisms such as animals and plants.^[7]
PAHs (Polycyclic Aromatic Hydrocarbon) in large bodies of water contaminated by oil spills or leaks. Many of the PAHs are carcinogens and are extremely toxic. They are regulated by concentration (ppb) using environmental chemistry and chromatography laboratory testing.
Nutrients leaching from agricultural land into water courses, which can lead to algal blooms and eutrophication.^[8]
Urban runoff of pollutants washing off impervious surfaces (roads, parking lots, and rooftops) during rain storms. Typical pollutants include gasoline, motor oil and other hydrocarbon compounds, metals, nutrients and sediment (soil).^[9]
Organometallic compounds.^[10]

Methods

Quantitative chemical analysis is a key part of environmental chemistry, since it provides the data that frame most environmental studies.^[11]

Common analytical techniques used for quantitative determinations in environmental chemistry include classical wet chemistry, such as gravimetric, titrimetric and electrochemical methods. More sophisticated approaches are used in the determination of trace metals and organic compounds. Metals are commonly measured by atomic spectroscopy and mass spectrometry: Atomic Absorption Spectrophotometry (AAS) and Inductively Coupled Plasma Atomic Emission (ICP-AES) or Inductively Coupled Plasma Mass Spectrometric (ICP-MS) techniques. Organic compounds, including PAHs, are commonly measured also using mass spectrometric methods, such as Gas chromatography-mass spectrometry (GC/MS) and Liquid chromatography-mass spectrometry (LC/MS). Tandem Mass spectrometry MS/MS and High Resolution/Accurate Mass spectrometry HR/AM offer sub part per trillion detection. Non-MS methods using GCs and LCs having universal or specific detectors are still staples in the arsenal of available analytical tools.

Other parameters often measured in environmental chemistry are radiochemicals. These are pollutants which emit radioactive materials, such as alpha and beta particles, posing danger to human health and the environment. Particle counters and Scintillation counters are most commonly used for these measurements. Bioassays and immunoassays are utilized for toxicity evaluations of chemical effects on various organisms. Polymerase Chain Reaction PCR is able to identify species of bacteria and other organisms through specific DNA and RNA gene isolation and amplification and is showing promise as a valuable technique for identifying environmental microbial contamination.

Published analytical methods

Peer-reviewed test methods have been published by government agencies^[12]^[13] and private research organizations.^[14] Approved published methods must be used when testing to demonstrate compliance with regulatory requirements.

Notable environmental chemists

Joan Berkowitz
Paul Crutzen (Nobel Prize in Chemistry, 1995)
Philip Gschwend
Alice Hamilton
John M. Hayes
Charles David Keeling
Ralph Keeling
Mario Molina (Nobel Prize in Chemistry, 1995)
James J. Morgan
Clair Patterson
Roger Revelle
Sherry Roland (Nobel Prize in Chemistry, 1995)
Robert Angus Smith
Susan Solomon
Werner Stumm
Ellen Swallow Richards
Hans Suess
John Tyndall

References

^ Williams, Ian. Environmental Chemistry, A Modular Approach. Wiley. 2001. ISBN 0-471-48942-5
^ "Glossary to the Buzzards Bay Watershed Management Plan". Archived from the original on 2016-10-09. Retrieved 2006-03-23.
^ American Meteorological Society. Glossary of Meteorology Archived 2011-09-20 at the Wayback Machine
^ North Carolina State University. Department of Soil Science. "Glossary." Archived 2014-09-18 at the Wayback Machine
^ Global Resource Action Center for the Environment (GRACE). New York, NY. Sustainable Table: Dictionary Archived 2012-08-24 at the Wayback Machine
^ Harrison, R.M (edited by). Understanding Our Environment, An Introduction to Environmental Chemistry and Pollution, Third Edition. Royal Society of Chemistry. 1999. ISBN 0-85404-584-8
^ Briffa, Jessica; Sinagra, Emmanuel; Blundell, Renald (September 8, 2020). "Heavy metal pollution in the environment and their toxicological effects on humans". Heliyon. 6 (9).
^ United States Environmental Protection Agency (EPA). Washington, DC. "Protecting Water Quality from Agricultural Runoff." Document No. EPA 841-F-05-001. March 2005.
^ EPA. "Protecting Water Quality from Urban Runoff." Document No. EPA 841-F-03-003. February 2003.
^ Sigel, A. (2010). Sigel, H.; Sigel, R.K.O. (eds.). Organometallics in Environment and Toxicology. Metal Ions in Life Sciences. Vol. 7. Cambridge: RSC publishing. ISBN 978-1-84755-177-1.
^ vanLoon, Gary W.; Duffy, Stephen J. (2000). Environmental Chemistry. Oxford: Oxford. pp. 7. ISBN 0-19-856440-6.
^ "Clean Water Act Analytical Methods". EPA. 2022-07-27.
^ "Hazardous Waste Test Methods / SW-846". EPA. 2022-06-15.
^ Eaton, Andrew D.; Greenberg, Arnold E.; Rice, Eugene W.; Clesceri, Lenore S.; Franson, Mary Ann H., eds. (2005). Standard Methods For the Examination of Water and Wastewater (21 ed.). American Public Health Association. ISBN 978-0-87553-047-5. Also available on CD-ROM and online by subscription.

External links

List of links for Environmental Chemistry - from the WWW Virtual Library
International Journal of Environmental Analytical Chemistry

[Williams-1] Williams, Ian. Environmental Chemistry, A Modular Approach. Wiley. 2001. ISBN 0-471-48942-5

[2] "Glossary to the Buzzards Bay Watershed Management Plan". Archived from the original on 2016-10-09. Retrieved 2006-03-23.

[3] American Meteorological Society. Glossary of Meteorology Archived 2011-09-20 at the Wayback Machine

[4] North Carolina State University. Department of Soil Science. "Glossary." Archived 2014-09-18 at the Wayback Machine

[5] Global Resource Action Center for the Environment (GRACE). New York, NY. Sustainable Table: Dictionary Archived 2012-08-24 at the Wayback Machine

[harrison-6] Harrison, R.M (edited by). Understanding Our Environment, An Introduction to Environmental Chemistry and Pollution, Third Edition. Royal Society of Chemistry. 1999. ISBN 0-85404-584-8

[7] Briffa, Jessica; Sinagra, Emmanuel; Blundell, Renald (September 8, 2020). "Heavy metal pollution in the environment and their toxicological effects on humans". Heliyon. 6 (9).

[8] United States Environmental Protection Agency (EPA). Washington, DC. "Protecting Water Quality from Agricultural Runoff." Document No. EPA 841-F-05-001. March 2005.

[9] EPA. "Protecting Water Quality from Urban Runoff." Document No. EPA 841-F-03-003. February 2003.

[10] Sigel, A. (2010). Sigel, H.; Sigel, R.K.O. (eds.). Organometallics in Environment and Toxicology. Metal Ions in Life Sciences. Vol. 7. Cambridge: RSC publishing. ISBN 978-1-84755-177-1.

[vanLoonDuffyp7-11] vanLoon, Gary W.; Duffy, Stephen J. (2000). Environmental Chemistry. Oxford: Oxford. pp. 7. ISBN 0-19-856440-6.

[12] "Clean Water Act Analytical Methods". EPA. 2022-07-27.

[13] "Hazardous Waste Test Methods / SW-846". EPA. 2022-06-15.

[14] Eaton, Andrew D.; Greenberg, Arnold E.; Rice, Eugene W.; Clesceri, Lenore S.; Franson, Mary Ann H., eds. (2005). Standard Methods For the Examination of Water and Wastewater (21 ed.). American Public Health Association. ISBN 978-0-87553-047-5. Also available on CD-ROM and online by subscription.

[1]

[2]

[3]

[4]

[5]

[6]

[7]

[8]

[9]

[10]

[11]

[12]

[13]

[14]

Environmental science
Main fields	Atmospheric science Biogeochemistry Ecology Environmental chemistry Geosciences Hydrology Limnology Oceanography Soil science
Related fields	Biology Chemistry green Ecological economics Environmental design Environmental economics Environmental engineering Environmental health epidemiology Environmental studies Environmental humanities Environmental statistics Environmental toxicology Geodesy Physics Radioecology Sustainability science Systems ecology Urban ecology
Applications	Energy conservation Environmental technology Natural resource management Pollution control Public transport encouragement Recycling Remediation Renewable energy Road ecology Sewage treatment Urban metabolism Water purification Waste management
Lists	Degrees Journals Research institutes Glossary Environment by year
See also	Human impact on the environment Sustainability Technogaianism
Category scientists Commons Environment portal WikiProject

Branches of chemistry
Glossary of chemical formulae List of biomolecules List of inorganic compounds Periodic table
Analytical	Instrumental chemistry Electroanalytical methods Spectroscopy IR Raman UV-Vis NMR Mass spectrometry EI ICP MALDI Separation process Chromatography GC HPLC Crystallography Characterization Titration Wet chemistry Calorimetry Elemental analysis
Theoretical	Quantum chemistry Computational chemistry Mathematical chemistry Molecular modelling Molecular mechanics Molecular dynamics Molecular geometry VSEPR theory
Physical	Electrochemistry Spectroelectrochemistry Photoelectrochemistry Thermochemistry Chemical thermodynamics Surface science Interface and colloid science Micromeritics Cryochemistry Sonochemistry Structural chemistry Chemical physics Molecular physics Femtochemistry Chemical kinetics Spectroscopy Photochemistry Spin chemistry Microwave chemistry Equilibrium chemistry Mechanochemistry
Inorganic	Coordination chemistry Magnetochemistry Organometallic chemistry Organolanthanide chemistry Cluster chemistry Solid-state chemistry Ceramic chemistry
Organic	Stereochemistry Alkane stereochemistry Physical organic chemistry Organic reactions Organic synthesis Retrosynthetic analysis Enantioselective synthesis Total synthesis / Semisynthesis Fullerene chemistry Polymer chemistry Petrochemistry Dynamic covalent chemistry
Biological	Biochemistry Molecular biology Cell biology Chemical biology Bioorthogonal chemistry Medicinal chemistry Pharmacology Clinical chemistry Neurochemistry Bioorganic chemistry Bioorganometallic chemistry Bioinorganic chemistry Biophysical chemistry
Interdisciplinarity	Nuclear chemistry Radiochemistry Radiation chemistry Actinide chemistry Cosmochemistry / Astrochemistry / Stellar chemistry Geochemistry Biogeochemistry Photogeochemistry Environmental chemistry Atmospheric chemistry Ocean chemistry Clay chemistry Carbochemistry Food chemistry Carbohydrate chemistry Food physical chemistry Agricultural chemistry Soil chemistry Chemistry education Amateur chemistry General chemistry Clandestine chemistry Forensic chemistry Forensic toxicology Post-mortem chemistry Nanochemistry Supramolecular chemistry Chemical synthesis Green chemistry Click chemistry Combinatorial chemistry Biosynthesis Chemical engineering Stoichiometry Materials science Metallurgy Ceramic engineering Polymer science
See also	History of chemistry Nobel Prize in Chemistry Timeline of chemistry of element discoveries "The central science" Chemical reaction Catalysis Chemical element Chemical compound Atom Molecule Ion Chemical substance Chemical bond Alchemy Quantum mechanics
Category Commons Portal WikiProject

Sustainability
Outline Index
Principles	Anthropocene Environmentalism Global governance Human impact on the environment Planetary boundaries Development
Consumption	Anthropization Anti-consumerism Circular economy Durable good Earth Overshoot Day Ecological footprint Ethical Green consumption Micro-sustainability Over-consumption Product stewardship Simple living Social return on investment Steady-state economy Sustainability Advertising Brand Marketing myopia Sustainable Consumer behaviour Market Systemic change resistance Tragedy of the commons
World population	Demographic transition Family planning Control Sustainable population
Technology	Appropriate Environmental technology Natural building Sustainable architecture Sustainable design Sustainable industries Sustainable packaging
Biodiversity	Biosecurity Biosphere Conservation biology Endangered species Holocene extinction Invasive species
Energy	Carbon footprint Renewable energy Sustainable energy
Food	Civic agriculture Climate-smart agriculture Community-supported agriculture Cultured meat Sustainable agriculture Sustainable diet Sustainable fishery
Water	Air well (condenser) Bioretention Bioswale Blue roof Catchwater Constructed wetland Detention basin Dew pond Footprint Hydroelectricity Hydropower Infiltration basin Irrigation tank Marine energy Micro hydro Ocean thermal energy conversion Pico hydro Rain garden Rainwater harvesting Rainwater tank Reclaimed water Retention basin Run-of-the-river hydroelectricity Scarcity Security Small hydro Sustainable drainage system Tidal power Tidal stream generator Tree box filter Water conservation Water heat recycling Water recycling shower Water-sensitive urban design
Accountability	Corporate environmental responsibility Corporate social responsibility Environmental accounting Environmental full-cost accounting Environmental planning Sustainability Accounting Measurement Metrics and indices Reporting Standards and certification Sustainable yield
Applications	Advertising Art Business City Climate finance Community Disinvestment Eco-capitalism Eco-cities Eco-investing Eco-socialism Ecovillage Environmental finance Green economy Construction Fashion Finance Gardening Geopark Green Development Infrastructure Marketing Green roof Greening Impact investing Landscape Livelihood Living Market Organic movement Organizations Procurement Refurbishment Socially responsible business Socially responsible marketing Sanitation Sourcing Space Sustainability organization Tourism Transport Urban drainage systems Urban infrastructure
Sustainable management	Environmental Fisheries Forest Humanistic capitalism Landscape Materials Natural resource Planetary Recycling Waste
Agreements and conferences	UN Conference on the Human Environment (Stockholm 1972) Brundtlandt Commission Report (1983) Our Common Future (1987) Earth Summit (1992) Rio Declaration on Environment and Development (1992) Agenda 21 (1992) Convention on Biological Diversity (1992) Lisbon Principles (1997) Earth Charter (2000) UN Millennium Declaration (2000) Earth Summit 2002 (Rio+10, Johannesburg) UN Conference on Sustainable Development (Rio+20, 2012) Sustainable Development Goals (2015)
Category Lists Science Studies Degrees